Al-La-Zr (Aluminum-Lanthanum-Zirconium)

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منابع مشابه

Precipitation evolution in Al–Zr and Al–Zr–Ti alloys during aging at 450–600 C

The transformation of Al3Zr (L12) and Al3(Zr1 xTix) (L12) precipitates to their respective equilibrium D023 structures is investigated in conventionally solidified Al–0.1Zr and Al–0.1Zr–0.1Ti (at.%) alloys aged isothermally at 500 C or aged isochronally in the range 300– 600 C. Titanium additions delay neither coarsening of the metastable L12 precipitates nor their transformation to the D023 st...

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Reactivity of the dinuclear fulvalene cyclopentadienyl zirconium cationic species [{Zr(

The dinuclear cationic zirconium compound [{Zr( -C5H5)}2( -CH2)( -Cl)( -C5H4-C5H4)][BMe(C6F5)3] 1 reacts in dichloromethane at −78 °C with three equivalents of RNC (R= Bu, 2,6-Me2C6H3) via insertion into the Zr-methylene bond to give the new zirconium cationic species [{Zr( -C5H5)}2(Cl)(CNBu){ -[ -CN(Bu)-CH2-CN(Bu)}( -C5H4-C5H4)][BMe(C6F5)3] 2 and [{Zr( -C5H5)}2(Cl){CN(2,6-Me2C6H3)}[ -{CN(2,6-M...

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Precipitation hardening in dilute Al–Zr alloys

The aim of this study was to investigate the effect of solute content (hipoperitectic Al–0.22 wt.%Zr and hiperperitectic Al–0.32 wt.%Zr) on the precipitation hardening and microstructural evolution of dilute Al–Zr alloys isothermally aged. The materials were conventionally cast in a muffle furnace, solidified in a water-cooled Cu mold and subsequently heat-treated at the temperature of 650 K (3...

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Precipitation evolution in Al–Zr and Al–Zr–Ti alloys during isothermal aging at 375–425 C

Formation of Al3Zr or Al3(Zr1 x Tix) precipitates with a metastable L12 structure was investigated in conventionally solidified A1–0.1 Zr, Al–0.2 Zr, Al–0.1 Zr–0.1 Ti, and Al–0.2 Zr–0.2 Ti (at.%) alloys aged isothermally at 375, 400, or 425 C. Pronounced hardening results from nanometer-scale, spheroidal Al3Zr or Al3(Zr1 xTix) (L12) precipitates within solute-enriched dendrites. Interdendritic ...

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Spontaneous nano-clustering of ZrO2 in atomic layer deposited LayZr1-yOx thin films: Part 1 – Material characterization

During atomic layer deposition (ALD) of uniform LayZr1-yOx thin films, spontaneous segregation of ZrO2 nanocrystals takes place that are embedded in an amorphous La2O3 matrix. This occurs if the Zr content in the LayZr1-yOx film is above 30% i.e. if the pulse ratio between the lanthanum precursor and the zirconium precursor is larger than six. We study this clustering phenomena using High resol...

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ژورنال

عنوان ژورنال: Journal of Phase Equilibria and Diffusion

سال: 2011

ISSN: 1547-7037,1863-7345

DOI: 10.1007/s11669-011-9862-5